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Safety Information

900717

Sigma-Aldrich

N-((1S,2S)-1-((R)-4-Isopropyl-4,5-dihydrooxazol-2-yl)-2-methylbutyl)acetamide

≥95%

Synonym(s):

Chiral APAO ligand

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About This Item

Empirical Formula (Hill Notation):
C13H24N2O2
Molecular Weight:
240.34
UNSPSC Code:
12352200
NACRES:
NA.22

Assay

≥95%

form

powder

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

color

white

functional group

amide

storage temp.

2-8°C

SMILES string

CC(C)[C@H]1N=C([C@@H](NC(C)=O)[C@@H](CC)C)OC1

Application

Chiral bidentate ligand developed by Jin-Quan Yu′s lab for enantioselective borylation of C(sp3)–H bonds. This acetyl-protected aminomethyl oxazoline (APAO) ligand was demonstrated to be compatible with carbocyclic substrates with both α-tertiary and α-quaternary carbon centers.

Other Notes

Pd(II)-Catalyzed Enantioselective C(sp3)–H Borylation

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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