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Safety Information

87860

Sigma-Aldrich

Tetramethylhydrazine

≥97.0%

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About This Item

Linear Formula:
(CH3)2NN(CH3)2
CAS Number:
Molecular Weight:
88.15
Beilstein:
1731483
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Quality Level

Assay

≥97.0%

form

liquid

impurities

≤2% water

refractive index

n20/D 1.404

density

0.777 g/mL at 20 °C (lit.)

SMILES string

CN(C)N(C)C

InChI

1S/C4H12N2/c1-5(2)6(3)4/h1-4H3

InChI key

DHBZRQXIRAEMRO-UHFFFAOYSA-N

Pictograms

Flame

Signal Word

Warning

Hazard Statements

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

80.6 °F - closed cup

Flash Point(C)

27 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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P A Craven et al.
Biochemical pharmacology, 34(17), 3101-3106 (1985-09-01)
A fatty acid stimulated, NADPH-independent pathway for the N-demethylation of 1,1-dimethylhydrazine (1,1-DMH) with the generation of HCHO was demonstrated in 10,000 g soluble fractions of colonic mucosal homogenates. Tetramethylhydrazine and, to a lesser extent, aminopyrine, but not 1,2-DMH or methylhydrazine
An electron spin resonance study of the novel radical cation produced during the horseradish peroxidase-catalyzed oxidation of tetramethylhydrazine.
B Kalyanaraman et al.
Biochemical and biophysical research communications, 105(1), 217-224 (1982-03-15)
B Kalyanaraman et al.
Carcinogenesis, 4(10), 1341-1343 (1983-10-01)
Prostaglandin endoperoxide synthase catalyzed the oxidation of tetramethylhydrazine to the tetramethylhydrazine radical cation, as detected by electron spin resonance spectroscopy. Oxidation of tetramethylhydrazine by prostaglandin endoperoxide synthase also resulted in the N-demethylation of tetramethylhydrazine leading to the formation of formaldehyde.

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