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804282

Sigma-Aldrich

SPhos Pd G4

Synonym(s):

(Methanesulfonato-κO)[2′-(methylamino)-2-biphenylyl]palladium - dicyclohexyl(2′,6′-dimethoxy-2-biphenylyl)phosphine

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About This Item

Empirical Formula (Hill Notation):
C40H50NO5PPdS
CAS Number:
Molecular Weight:
794.29
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

Quality Level

form

powder

feature

generation 4

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

SMILES string

CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.COC3=CC=CC(OC)=C3C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6

InChI

1S/C26H35O2P.C13H12N.CH4O3S.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h9-11,16-21H,3-8,12-15H2,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

ISSWOKPFLWDXSU-UHFFFAOYSA-M

General description

SPhos Pd G4 is a versatile 4th generation palladium precatalyst developed by Buchwald group.

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Articles

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

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