All Photos(1)
Synonym(s):
Garg 3-Bromobenzyne Precursor
Empirical Formula (Hill Notation):
C10H12BrF3O3SSi
CAS Number:
Molecular Weight:
377.25
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
95%
form
liquid
refractive index
n/D 1.492
density
1.482 g/L at 25 °C
storage temp.
2-8°C
SMILES string
O=S(OC1=C([Si](C)(C)C)C=CC=C1Br)(C(F)(F)F)=O
InChI
1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
InChI key
ZNKAHJCGEPVEBA-UHFFFAOYSA-N
Related Categories
Application
Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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