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Merck
CN

797774

Graphene nanoribbons

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About This Item

Linear Formula:
C
Molecular Weight:
12.01
EC Number:
231-153-3
UNSPSC Code:
12352103
NACRES:
NA.23

Key Documents

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Assay

≥90.0% carbon basis (TGA)

form

powder

L × W

2-15 μm × 40-250 nm

density

2.2745 g/mL (He gas method)

bulk density

0.0970 g/mL (Mercury Porosimetry)

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General description

Produced by unzipping multi-walled carbon nanotubes by potassium intercalation.

Application

  • Composites.
  • Conductive inks.
  • Electrodes for LiB.
  • Energy storage & harvesting applications.
  • Bio-medical applications.
  • Preferred dispersing organic solvents: pyrrolidones and chlorinated solvents.
  • Less preferred dispersing organic solvents: cyclohexanone and γ-butyrolactone.
  • Aqueous dispersions are possible at 0.1mg/mL with triton-X-100, sodium cholate and deoxycholate and cellulose-based surfactants.

Analysis Note

Raman Spectroscopic Data:
ID/IG = 0.65±0.07
I2D/IG = 0.74±0.03
2D FWHM = 63 cm-1

Legal Information

Graphene Nanoribbon Composites and Methods of Making the Same, WO/2012/112435 A1.

Pictograms

Health hazard
GHS08

Signal Word

Danger

Hazard Statements

H351,H361fd,H372

Hazard Classifications

Carc. 2 - Repr. 2 - STOT RE 1 Inhalation

Target Organs

Lungs

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

nwg

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Certificates of Analysis (COA)

Lot/Batch Number
MKCD0980
MKBX2277V

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High Throughput Preparation of Large Area Transparent Electrodes Using Non-Functionalized Graphene Naroribbons.
Zhu Y, et al.
Chemistry of Materials, 23, 935-939 (2011)
Dmitry V Kosynkin et al.
ACS nano, 5(2), 968-974 (2011-01-06)
Here we demonstrate that graphene nanoribbons (GNRs) free of oxidized surfaces can be prepared in large batches and 100% yield by splitting multiwalled carbon nanotubes (MWCNTs) with potassium vapor. If desired, exfoliation is attainable in a subsequent step using chlorosulfonic
Lei Li et al.
Advanced materials (Deerfield Beach, Fla.), 25(43), 6298-6302 (2013-09-03)
A facile and cost-effective approach for the fabrication of a hierarchical nanocomposite material of graphene-wrapped MnO2 -graphene nanoribbons (GMG) is developed. The resulting composite has a high specific capacity and an excellent cycling stability owing to the synergistic combination of
Changsheng Xiang et al.
ACS nano, 7(11), 10380-10386 (2013-10-10)
A thermoplastic polyurethane (TPU) composite film containing hexadecyl-functionalized low-defect graphene nanoribbons (HD-GNRs) was produced by solution casting. The HD-GNRs were well distributed within the polyurethane matrix, leading to phase separation of the TPU. Nitrogen gas effective diffusivity of TPU was
Lei Li et al.
ACS applied materials & interfaces, 5(14), 6622-6627 (2013-06-25)
A facile and cost-effective approach to the fabrication of a nanocomposite material of polyaniline (PANI) and graphene nanoribbons (GNRs) has been developed. The morphology of the composite was characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron microscopy, and
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