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Merck
CN

794503

Ritter Trifluoroiodomethane-DMSO Reagent

Synonym(s):

2DMSO-CF3I, DMSO-trifluoromethyl iodide adduct

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About This Item

Empirical Formula (Hill Notation):
C5H12F3IO2S2
Molecular Weight:
352.18
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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SMILES string

FC(F)(F)I.CS(C)=O.CS(C)=O

InChI

1S/2C2H6OS.CF3I/c2*1-4(2)3;2-1(3,4)5/h2*1-2H3;

InChI key

MMNWUCHAIFIKKV-UHFFFAOYSA-N

assay

95%

form

liquid

reaction suitability

reaction type: C-C Bond Formation

refractive index

n/D 1.466

density

1.529 at 25 °C

functional group

fluoro
iodo
sulfoxide

shipped in

dry ice

storage temp.

2-8°C

Application

Product is a more convenient, liquified version of trifluoroiodomethane, which can be utilized in photocatalytic and electrophilic pentafluoroethylation of olefins and heteroatoms respectively.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

214.0 °F

flash_point_c

101.11 °C

Regulatory Information

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The Ritter lab currently focuses on fluorination chemistry for late-stage functionalization of complex natural and unnatural products. PhenoFluor™ has been developed as a general reagent for the selective, predictable, direct deoxyfluorination of complex alcohols and phenols.

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