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791393

Sigma-Aldrich

C106 Dye

≥85% (HPLC)

Synonym(s):

Greatcell Solar®, Ruthenate(2-), [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)- N1,N1′][4,4′-bis[5-(hexylthio)-2-thienyl]-2,2′-bipyridine- N1,N1′]bis(thiocyanato-N)-, cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)

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About This Item

CAS Number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

≥85% (HPLC)

form

powder (black)

λmax

313 +/- 15 nm at 0.02 mM in DMF
348 +/- 15 nm at 0.02 mM in DMF
540 +/- 15 nm at 0.02 mM in DMF

SMILES string

OC(C1=CC(C2=CC(C(O)=O)=CC=N2)=NC=C1)=O.S=C=N[Ru]N=C=S.CCCCCCSC(S3)=CC=C3C4=CC(C5=CC(C6=CC=C(SCCCCCC)S6)=CC=N5)=NC=C4

InChI

1S/C30H36N2S4.C12H8N2O4.2CNS.Ru/c1-3-5-7-9-19-33-29-13-11-27(35-29)23-15-17-31-25(21-23)26-22-24(16-18-32-26)28-12-14-30(36-28)34-20-10-8-6-4-2;15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h11-18,21-22H,3-10,19-20H2,1-2H3;1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI key

ZEXAHKWZTIWSCT-UHFFFAOYSA-N

Application

A ruthenium dye for high-efficiency dye-sensitized solar cells

Power conversion efficiencies of 11.7-12.1% achieved in high-efficiency dye-sensitized solar cells under air-mass 1.5G simulated sunlights.

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Qingjiang Yu et al.
ACS nano, 4(10), 6032-6038 (2010-10-07)
We present a time-saving staining protocol based upon the low-toxicity and nonvolatile solvent dimethyl sulfoxide for a high-efficiency dye-sensitized solar cell, which is very critical for the roll-to-roll flexible cell production. Power conversion efficiencies of 11.7-12.1% were achieved under AM1.5G

Articles

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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