790850
(S)-3,3′-Bis(4-trifluoromethylphenyl)-1,1′-binaphthyl-2,2′-disulfonimide
Synonym(s):
(11bS)-2,6-Bis[4-(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
About This Item
form
solid
reaction suitability
reaction type: Aldol Reaction
reaction type: Allylation
reaction type: Carbonyl/Imine Addition
reaction type: Friedel-Crafts Alkylation
mp
340-360 °C
SMILES string
O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC=C(C(F)(F)F)C=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC=C(C(F)(F)F)C=C7)(N5)=O
InChI
1S/C34H19F6NO4S2/c35-33(36,37)23-13-9-19(10-14-23)27-17-21-5-1-3-7-25(21)29-30-26-8-4-2-6-22(26)18-28(20-11-15-24(16-12-20)34(38,39)40)32(30)47(44,45)41-46(42,43)31(27)29/h1-18,41H
InChI key
FQLCMGCITBTGMR-UHFFFAOYSA-N
Application
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
Certificates of Analysis (COA)
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Articles
Asymmetric counteranion-directed catalysis (ACDC) has a number of valuable applications in enantioselective synthesis.
Related Content
The List group focuses on the development of new concepts in catalysis. Since 1999, this research group has pioneered the development of organocatalysis as the third pillar of stereoselective catalysis, along side biocatalysis and transition metal catalysis.
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