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Merck
CN

778362

5-Methyl-5-allyloxycarbonyl-1,3-dioxan-2-one

97%

Synonym(s):

5-Methyl-2-oxo-1,3-dioxane-5-carboxylic acid, 2-propen-1-yl ester, Allyl 5-methyl-2-oxo-1,3-dioxane-5-carboxylate, Allyl functionalized carbonate monomer, MAC

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About This Item

Empirical Formula (Hill Notation):
C9H12O5
CAS Number:
Molecular Weight:
200.19
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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InChI

1S/C9H12O5/c1-3-4-12-7(10)9(2)5-13-8(11)14-6-9/h3H,1,4-6H2,2H3

SMILES string

O=C1OCC(C(OCC=C)=O)(C)CO1

InChI key

OPWZLMZGHGAFNG-UHFFFAOYSA-N

assay

97%

form

solid

mp

65-70 °C

storage temp.

−20°C

Application

This monomer contains a pendant allyl group for thiol-ene click chemistry; to be copolymerized with lactides or glycolides for biodegradable polymers containing pendant functional groups.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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The Crabtree positive yeasts, such as Saccharomyces cerevisiae, prefer fermentation to respiration, even under fully aerobic conditions. The selective pressures that drove the evolution of this trait remain controversial because of the low ATP yield of fermentation compared to respiration.
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Epigenetic information, which can be passed on independently of the DNA sequence, is stored in part in the form of histone posttranslational modifications and specific histone variants. Although complexes necessary for deposition have been identified for canonical and variant histones
M Coburn et al.
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