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Hoveyda-Grubbs Catalyst® M2001

Umicore

Synonym(s):

Grubbs Catalyst® Z-Selective, Hoveyda-Grubbs Catalyst® MZ1c (C633), Grubbs Catalyst® C633, Grubbs Z-Selective Metathesis Catalyst, Grubbs′ Z-Selective Catalyst, [2-(1-Methylethoxy-O)phenylmethyl-C](nitrato-O,O′){rel-(2R,5R,7R)-adamantane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-y lidene]}ruthenium, [2-(1-Methylethoxy-O)phenylmethyl-C](nitrato-O,O′){rel-(2R,5R,7S)-tricyclo[3.3.1.13,7]decane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-ylidene]}ruthenium

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About This Item

Empirical Formula (Hill Notation):
C32H41N3O4Ru
CAS Number:
1352916-84-7
Molecular Weight:
632.76
UNSPSC Code:
12161600
NACRES:
NA.22

Quality Level

100

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Olefin Metathesis

mp

200-215 °C

storage temp.

2-8°C

Related Categories

Application

Olefin Metathesis Catalyst for cis-selective ring-opening metathesis polymerization and Z-Selective Olefin Metathesis.

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Benjamin K Keitz et al.
Journal of the American Chemical Society, 134(1), 693-699 (2011-11-22)
Several new C-H-activated ruthenium catalysts for Z-selective olefin metathesis have been synthesized. Both the carboxylate ligand and the aryl group of the N-heterocyclic carbene have been altered and the resulting catalysts evaluated using a range of metathesis reactions. Substitution of
Benjamin K Keitz et al.
Journal of the American Chemical Society, 134(4), 2040-2043 (2012-01-14)
Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C-H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A

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