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Merck
CN

767654

cis-Dichlorobis(dimethyl sulfoxide)platinum(II)

97%, solid

Synonym(s):

cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)2Cl2

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About This Item

Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS Number:
Molecular Weight:
422.25
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

cis-Dichlorobis(dimethyl sulfoxide)platinum(II), 97%

SMILES string

Cl[Pt]Cl.CS(C)=O.CS(C)=O

InChI

1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2

InChI key

KDADQDWVKZJTDQ-UHFFFAOYSA-L

assay

97%

form

solid

reaction suitability

core: platinum, reagent type: catalyst

mp

218-224 °C

Quality Level

General description

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.

Application

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:
  • Catalyst in the oleum-mediated (SO3-H2SO4) methane oxidation to form methyl bisulfate (MBS).
  • Precursor in the synthesis of cyclometalated complexes.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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H Nakagawa et al.
Journal of neuro-oncology, 16(1), 61-67 (1993-04-01)
The distribution of cis-diamminedichloroplatinum (CDDP) was studied in 23 patients undergoing surgical resection of brain tumors metastatic from lung cancer. CDDP (100 mg/m2) was administered intravenously (i.v.) or intra-arterially (IA) at the time of surgery, and various fluids and tissues
M Imaizumi et al.
Surgery today, 23(5), 412-419 (1993-01-01)
Human tumors transplanted into nude mice have long been used to assess the effectiveness of antitumor drugs and yet there is still no established standard method in preclinical practice for screening new antitumor drugs in vivo using nude mice. Thus
Pt (II) Cl2 (DMSO) 2-catalyzed cross-coupling of polyfluoroaryl imines
Sun AD, et al.
Journal of Fluorine Chemistry, 131(11), 1237-1240 (2010)
Synthesis, characterization, and photophysical properties of cyclometalated N-Heterocyclic carbene platinum (II) complexes
Mastrocinque F, et al.
Journal of Organometallic Chemistry, 880, 98-107 (2019)
Osteosarcoma in adolescents and young adults: new developments and controversies. Thermal chemosensitization of cDDP-resistant cells.
A W Konings et al.
Cancer treatment and research, 62, 93-100 (1993-01-01)

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