767654
cis-Dichlorobis(dimethyl sulfoxide)platinum(II)
97%, solid
Synonym(s):
cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)2Cl2
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About This Item
Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS Number:
Molecular Weight:
422.25
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
cis-Dichlorobis(dimethyl sulfoxide)platinum(II), 97%
SMILES string
Cl[Pt]Cl.CS(C)=O.CS(C)=O
InChI
1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
InChI key
KDADQDWVKZJTDQ-UHFFFAOYSA-L
assay
97%
form
solid
reaction suitability
core: platinum, reagent type: catalyst
mp
218-224 °C
Quality Level
Related Categories
General description
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.
Application
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:
- Catalyst in the oleum-mediated (SO3-H2SO4) methane oxidation to form methyl bisulfate (MBS).
- Precursor in the synthesis of cyclometalated complexes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Enhanced catalytic activity of (DMSO) 2PtCl2 for the methane oxidation in the SO3-H2SO4 system
Dang H, et al
ACS Catalysis, 8(12), 11854-11862 (2018)
J L Schwartz et al.
Cancer chemotherapy and pharmacology, 29(3), 207-213 (1992-01-01)
Dietary levels of beta-carotene and vitamin E have been associated with cancer prevention and to a lesser extent, with therapeutic enhancement of cancer treatment. We report on the cytotoxicity of beta-carotene, vitamin E, and the combination of beta-carotene and vitamin
R Gorodetsky et al.
Medical physics, 20(4), 1007-1012 (1993-07-01)
Noninvasive analysis of heavy elements in external tissues by diagnostic-x-ray spectrometry (DXS) is presented. Pt can be detected accurately with sensitivity below 1 microgram/g wet weight of tissue. In the present paper the possibility to monitor Pt accumulation and clearance
K R Grigorian et al.
Biofizika, 56(1), 31-34 (2011-03-30)
The interaction of cis-[PtCl2(Me2SO)2] with human serum albumin (HSA) and the sensitivity of the complex towards the thermal denaturation depending on the duration of incubation have been studied by absorption and fluorescence spectroscopy methods. Optimum conditions for cis-[PtCl2(Me2SO)2] binding to
Pt (II) Cl2 (DMSO) 2-catalyzed cross-coupling of polyfluoroaryl imines
Sun AD, et al.
Journal of Fluorine Chemistry, 131(11), 1237-1240 (2010)
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