767654
cis-Dichlorobis(dimethyl sulfoxide)platinum(II)
97%, solid
Synonym(s):
cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)2Cl2
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About This Item
Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS Number:
Molecular Weight:
422.25
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
cis-Dichlorobis(dimethyl sulfoxide)platinum(II), 97%
SMILES string
Cl[Pt]Cl.CS(C)=O.CS(C)=O
InChI
1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
InChI key
KDADQDWVKZJTDQ-UHFFFAOYSA-L
assay
97%
form
solid
reaction suitability
core: platinum, reagent type: catalyst
mp
218-224 °C
Quality Level
Related Categories
General description
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.
Application
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:
- Catalyst in the oleum-mediated (SO3-H2SO4) methane oxidation to form methyl bisulfate (MBS).
- Precursor in the synthesis of cyclometalated complexes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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H Nakagawa et al.
Journal of neuro-oncology, 16(1), 61-67 (1993-04-01)
The distribution of cis-diamminedichloroplatinum (CDDP) was studied in 23 patients undergoing surgical resection of brain tumors metastatic from lung cancer. CDDP (100 mg/m2) was administered intravenously (i.v.) or intra-arterially (IA) at the time of surgery, and various fluids and tissues
M Imaizumi et al.
Surgery today, 23(5), 412-419 (1993-01-01)
Human tumors transplanted into nude mice have long been used to assess the effectiveness of antitumor drugs and yet there is still no established standard method in preclinical practice for screening new antitumor drugs in vivo using nude mice. Thus
Pt (II) Cl2 (DMSO) 2-catalyzed cross-coupling of polyfluoroaryl imines
Sun AD, et al.
Journal of Fluorine Chemistry, 131(11), 1237-1240 (2010)
Synthesis, characterization, and photophysical properties of cyclometalated N-Heterocyclic carbene platinum (II) complexes
Mastrocinque F, et al.
Journal of Organometallic Chemistry, 880, 98-107 (2019)
Osteosarcoma in adolescents and young adults: new developments and controversies. Thermal chemosensitization of cDDP-resistant cells.
A W Konings et al.
Cancer treatment and research, 62, 93-100 (1993-01-01)
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