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763705

Sigma-Aldrich

Graphene oxide

greener alternative

2 mg/mL, dispersion in H2O, avg. no. of layers, 1

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Synonym(s):
graphene oxide aqueous dispersion
Linear Formula:
CxOyHz
UNSPSC Code:
12352103
NACRES:
NA.23

form

dispersion in H2O

Quality Level

100

feature

avg. no. of layers 1

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

2 mg/mL

refractive index

n20/D 1.333

density

0.981 g/mL at 25 °C

greener alternative category

, Enabling

SMILES string

O=C(O)C1C2=C3C4=C5C6=C7C8=C9C%10=C%11C(C%12=C%13C%10=C%14C8=C%15C6=C%16C4=C%17C2=CC(C(O)=O)C%18=C%17C%19=C%16C%20=C%15C%21=C%14C%22=C%13C(C%23=C%24C%22=C%25C%21=C%26C%20=C%27C%19=C%28C%18=CC(C(O)=O)C%29=C%28C%30=C%27C%31=C%26C%32=C%25C%33=C%24C(C%34=C%35C

InChI

1S/C140H42O20/c141-131(142)26-13-23-15-44-62(140(159)160)45-16-24-14-40-31(132(143)144)5-1-29-41-20-48(135(149)150)56-33-7-3-28-27-2-6-32-55-37(133(145)146)11-9-35-60(138(155)156)42-17-25-18-43-61(139(157)158)36-10-12-38(134(147)148)58-46-21-50(137(153)154)59-47-22-49(136(151)152)57-34-8-4-30-39(19-26)51(23)78-72(44)88-75(45)80-52(24)79(54(29)40)95-71(41)83(56)101-93-69(33)64(28)91-90-63(27)68(32)92-86(66(35)55)73(42)81-53(25)82-74(43)87(67(36)58)96-76(46)85(59)103-97-77(47)84(57)102-94-70(34)65(30)89(78)105-104(88)115-98(80)111(95)116(101)126-122-110(93)107(91)120-119-106(90)108(92)99(81)114-100(82)112(96)118(103)128(124(114)119)123-113(97)117(102)127(130(122)129(120)123)121(109(94)105)125(115)126/h2,5,7-10,12-22,26,38,48-50H,1,3-4,6,11H2,(H,141,142)(H,143,144)(H,145,146)(H,147,148)(H,149,150)(H,151,152)(H,153,154)(H,155,156)(H,157,158)(H,159,160)

InChI key

VTWITIAIMADGRM-UHFFFAOYSA-N

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General description

  • Chloride free (purified by dialysis)
  • Monolayer sheet
  • sheet diameter <10 micron
Graphene oxide (GO) is a one atom thick 2D carbon material with excellent thermal, mechanical, and electrical properties due to its unique structural and morphological features. GO can be easily dispersed in aqueous and polar organic solvents to facilitate its practical use. It can be synthesized by modified Hummer’s method. It can be applied in the fields of drug delivery, energy storage, oil-water separation, immobilization catalysis, desalination, and solar cells.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". High concentrated graphene oxide sheets provide the prerequisite viscosity to bind the electrode materials together and enable 3D printing. Using water as a green solvent makes this aqueous ink system feasible for processing and drying safety and low cost. Click here for more information.

Application

Because of the presence of oxygen-containing functional groups and acidic nature, GO can serve as both carbocatalyst as well as a supporting scaffold for various catalytically active species. GO can facilitate many organic transformations such as the oxidation of sulfides, olefins, and various hydrocarbons, Friedel–Crafts reaction, Aza–Michael additions, condensation, and ring-opening polymerization.

It can be used as a support for biocatalysis in organic solvents. For example, carboxyl-functionalized graphene oxide can act as a support to immobilize Yarrowia lipolytica lipase. The immobilized enzyme exhibits a high efficiency for the resolution of the racemic compound in the organic solvent.

It can also be used as a hole transport layer in organic photovoltaic cells.

Features and Benefits

  • Good solution processability
  • Hydrophilic and easily dispersed in water
  • Low production cost
  • Presence of rich active oxygen-containing functional groups
  • It can be easily functionalized
Large surface area, high chemical stability, good charge carrier properties.

Preparation Note

Product may aggregate over time to form larger particles. Sonicate before use if single layer graphene oxide required.

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Kaiying Cheng et al.
Nature structural & molecular biology, 27(1), 71-77 (2020-01-08)
The RecBCD complex plays key roles in phage DNA degradation, CRISPR array acquisition (adaptation) and host DNA repair. The switch between these roles is regulated by a DNA sequence called Chi. We report cryo-EM structures of the Escherichia coli RecBCD
N-doped graphitic self-encapsulation for high performance silicon anodes in lithium-ion batteries.
JunaLee, Won, et al.
Energy & Environmental Science, 7(2), 621-626 (2014)
Goki Eda et al.
Advanced materials (Deerfield Beach, Fla.), 22(22), 2392-2415 (2010-05-01)
Chemically derived graphene oxide (GO) possesses a unique set of properties arising from oxygen functional groups that are introduced during chemical exfoliation of graphite. Large-area thin-film deposition of GO, enabled by its solubility in a variety of solvents, offers a
Jin Ok Hwang et al.
ACS nano, 6(1), 159-167 (2011-12-14)
Graphene is a promising candidate to complement brittle and expensive transparent conducting oxides. Nevertheless, previous research efforts have paid little attention to reduced graphene, which can be of great benefit due to low-cost solution processing without substrate transfer. Here we
Toward N-doped graphene via solvothermal synthesis
Deng, Dehui, et al.
Chemistry of Materials, 23(5), 1188-1193 (2011)
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