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Sigma-Aldrich

Palladium(II) nitrate dihydrate

~40% Pd basis

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Synonym(s):
Palladium dinitrate hydrate
Linear Formula:
Pd(NO3)2 · 2H2O
CAS Number:
32916-07-7
Molecular Weight:
266.46
EC Number:
233-265-8
MDL number:
MFCD00149819
UNSPSC Code:
12352302
PubChem Substance ID:
57652616
NACRES:
NA.23

Quality Level

100

form

powder or crystals

reaction suitability

reagent type: catalyst
core: palladium

concentration

~40% Pd

SMILES string

O.O.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.2H2O.Pd/c2*2-1(3)4;;;/h;;2*1H2;/q2*-1;;;+2

InChI key

JUBNUQXDQDMSKL-UHFFFAOYSA-N

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General description

Palladium(II) nitrate dihydrate is a highly reactive compound that is commonly used in catalytic reactions such as the hydrogenation of organic molecules, dehydrogenation of alkanes, and oxidation of alcohols. It is also used in the electrodeposition of palladium on surfaces and as a palladium source in the fabrication of palladium-containing materials.

It is also employed in the fabrication of low-cost solid-state hydrogen storage devices made of three-dimensional (3D) reduced graphene oxide (rGO) and expanded graphite (EG)nanocomposite (NC) decorated with Pd nanoparticles (NPs).

Application

Palladium(II) nitrate dehydrate is used as a reactant for:
  • Doping activated carbon for catalysis
  • Catalytic use of hydroxyapatite (HAP) supported Pd nanoclusters in the hydrolysis of ammonia-borane.

It′s used as catalyst for:
  • Selective hydrogenation of 1-heptyne and napthalene
  • In highly porous coordination polymer MIL-101 support.

It may also be used as a reactant for:
  • Preparation of platinum-palladium/carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells
  • Synthesis of Cu-Pd alloy thin films on Ti substrates by co-electrodeposition of Pd and Cu from nitrate-base electrolytic baths
  • Preparation of palladium catalyst supported on vertically aligned multi-walled carbon nanotubes for microwave-assisted Heck reactions of p-iodonitrobenzene with styrene and Et acrylate
  • Preparation of di-phenyl sulfide-modified Pd/TiO2 catalysts for acetylene hydrogenation

Signal Word

Danger

Hazard Statements

H271,H290,H302,H314,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 1 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Methanol-tolerant oxygen reduction reaction at Pt-Pd/C alloy nanocatalysts
Remona AM, et al.
Journal of Fuel Cell Science and Technology, 8(1) (2011)
Oxidative decomposition of naphthalene by supported metal catalysts
Zhang XW, et al.
Applied Catalysis A: General, 250(2), 341-352 (2003)
Pd/NH2-KIE-6 catalysts with exceptional catalytic activity for additive-free formic acid dehydrogenation at room temperature: Controlling Pd nanoparticle size by stirring time and types of Pd precursors
Min-Ho Jin, et al.
International Journal of Hydrogen Energy, 43, 1451-1458 (2018)
Design and Electrochemical Study of Three-Dimensional Expanded Graphite and Reduced Graphene Oxide Nanocomposites Decorated with Pd Nanoparticles for Hydrogen Storage
Emmanuel Boateng, et al.
The Journal of Physical Chemistry C, 125, 22970-22981 (2021)
A new recyclable Pd catalyst supported on vertically aligned carbon nanotubes for microwaves-assisted Heck reactions
Janowska I, et al.
Comptes Rendus Chimie, 14 (2011)
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