758388
Pyrazino[2,3-f][1,10]phenanthroline
99% (HPLC)
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About This Item
Empirical Formula (Hill Notation):
C14H8N4
CAS Number:
Molecular Weight:
232.24
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Product Name
Pyrazino[2,3-f][1,10]phenanthroline, 99% (HPLC)
InChI
1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H
SMILES string
c1cnc2c(c1)c3nccnc3c4cccnc24
InChI key
IBOSPAWVGHGUAV-UHFFFAOYSA-N
assay
99% (HPLC)
form
solid
mp
310-315 °C
Quality Level
Related Categories
Application
- As an electron accepting ligand in metal complexes which are used in solar cells.
- Used in the synthesis of ruthenium (II) complexes which are used as DNA probes.
Features and Benefits
Imparts improved directionality of electron transfer in excited copper complexes.
General description
Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.
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Ge; Hu; Wei;et al.
Journal of Luminescence, 131, 238-243 (2011)
Yujie Sun et al.
Inorganic chemistry, 47(14), 6427-6434 (2008-06-25)
A series of ruthenium(II) complexes possessing ligands with an extended pi system were synthesized and characterized. The complexes are derived from [Ru(bpy)3](2+) (1, bpy = 2,2'-bipyridine) and include [Ru(bpy)2(tpphz)](2+) (2, tpphz = tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine), [Ru(bpy)2(dppx)](2+) (3, dppx = 7,8-dimethyldipyrido[3,2-a:2',3'-c]phenazine), [Ru(bpy)2(dppm2)](2+) (4
Synthesis, spectroscopic and electrochemical characterization of copper (I) complexes with functionalized pyrazino [2, 3-f]-1, 10-phenanthroline.
Barrientos, L., Araneda, C., Loeb, B., & Crivelli, I. G.
Polyhedron, 27(4), 1287-1295 (2008)
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