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754730

Sigma-Aldrich

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate

97%

Synonym(s):

Ru(bpy)3(PF6)2, Ruthenium-tris(2,2′-bipyridyl) dihexafluorophosphate

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1 G
¥604.52

¥604.52

List Price¥2,015.06Save 70%

Available to ship on2025年4月16日Details

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1 G
¥604.52

About This Item

Empirical Formula (Hill Notation):
C30H24F12N6P2Ru
CAS Number:
60804-74-2
Molecular Weight:
859.55
MDL number:
MFCD11042502
UNSPSC Code:
12352103
PubChem Substance ID:
329766452
NACRES:
NA.23

¥604.52

List Price¥2,015.06Save 70%

Available to ship on2025年4月16日Details

Request a Bulk Order

Assay

97%

form

solid

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

impurities

(Material is not fluorescence active.)

mp

>300 °C

photocatalyst activation

425 nm

absorption

13,400 at 456 nm
80,000 at 291 nm

SMILES string

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2

InChI key

KLDYQWXVZLHTKT-UHFFFAOYSA-N

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三（2,2′——联吡啶二氯钌 (II) 六水合物

双(2,2-二吡啶)-(5-氨基邻二氮杂菲)双(六氟磷酸)钌 BioReagent, suitable for fluorescence

90819

双(2,2-二吡啶)-(5-氨基邻二氮杂菲)双(六氟磷酸)钌

form

solid

form

powder

form

-

form

powder

reaction suitability

core: ruthenium

reaction suitability

core: ruthenium, reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

-

reaction suitability

core: ruthenium, reaction type: Photocatalysis, reagent type: catalyst

impurities

(Material is not fluorescence active.)

impurities

-

impurities

-

impurities

-

mp

>300 °C

mp

>300 °C (lit.)

mp

>300 °C (lit.)

mp

-

photocatalyst activation

425 nm

photocatalyst activation

450 nm

photocatalyst activation

-

photocatalyst activation

-

General description

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate (Ru(bpy)3(PF6)2) is a conducting polymer that is majorly used as an active layer in electrochemical devices. It facilitates the formation of highly efficient and low voltage devices. It shows an external quantum efficiency of 0.35 and 400 cd/m2 at 3V.[1][2]

Application

Ru(bpy)3(PF6)2 may be used as a conjugating polymer in the development of light emitting electrochemical cell based devices such as light emitting diodes (LEDs).[3] It is also used as a high-efficiency triplet emitter for OLED/Sensor research.[4]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

  • Specification Sheet

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    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCV9409
    WXBF3950S
    MKCT5767
    MKCS2031
    MKCR1536

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    Find documentation for the products that you have recently purchased in the Document Library.

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    Silvia Voci et al.
    Analytical and bioanalytical chemistry, 412(17), 4067-4075 (2020-04-29)
    Nanofluidic electrochemical devices confine the volume of chemical reactions to femtoliters. When employed for light generation by electrochemiluminescence (ECL), nanofluidic confinement yields enhanced intensity and robust luminescence. Here, we investigate different ECL pathways, namely coreactant and annihilation ECL in a
    Wesley R Browne et al.
    Journal of the American Chemical Society, 125(7), 1706-1707 (2003-02-13)
    The excited-state properties of the transition metal complexes tris(2,2'-bipyridine) ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) are examined using picosecond time-resolved luminescence spectroscopy. For both complexes, direct observation of a short-lived high-energy emission with a lifetime of less than 4 ps is reported.
    Valentina Leandri et al.
    Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
    The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2
    Direct measurement of the electric-field distribution in a light-emitting electrochemical cell
    Slinker JD, et al.
    Testing, 6(11), 894-894 (2007)
    Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
    Buda, M
    Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
    View All Related Papers

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