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754013

Sigma-Aldrich

PFO-DBT

average Mw 10,000-50,000

Synonym(s):

Poly[2,7-(9,9-dioctylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]

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About This Item

Linear Formula:
(C43H46N2S3)n
CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.23

description

Band gap: 1.87 eV

Quality Level

form

solid

mol wt

average Mw 10,000-50,000

loss

0.5 wt. % TGA, 400 °C

transition temp

Tm >400 °C

Orbital energy

HOMO -5.4 eV 
LUMO -3.53  (CV)

OPV Device Performance

ITO/PEDOT:PSS/PFO-DPT:PC61BM (1:2)/Ba/Al

  • Short-circuit current density (Jsc): 5.18 mA/cm2
  • Open-circuit voltage (Voc): 0.95 V
  • Fill Factor (FF): 0.35
  • Power Conversion Efficiency (PCE): 2.24 %

semiconductor properties

P-type (mobility=3×10−4 cm2/V·s)

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Related Categories

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Fluorene-based low band-gap copolymers for high performance photovoltaic devices
Zhou, Q.; et al.
Applied Physics Letters, 84, 1653-1653 (2004)

Articles

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

Thin, lightweight, and flexible electronic devices meet widespread demand for scalable, portable, and robust technology.

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