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Merck
CN

752819

Zinc fluoride

99.999% trace metals basis

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About This Item

Linear Formula:
ZnF2
CAS Number:
Molecular Weight:
103.39
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
232-001-9
MDL number:
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InChI key

BHHYHSUAOQUXJK-UHFFFAOYSA-L

InChI

1S/2FH.Zn/h2*1H;/q;;+2/p-2

SMILES string

F[Zn]F

vapor pressure

1 mmHg ( 970 °C)

assay

99.999% trace metals basis

form

powder

mp

872 °C (lit.)

density

4.95 g/mL at 25 °C (lit.)

Application

Zinc Fluoride has been shown to aid in hydrogen release from NaBH4 and as a component in the synthesis of fluorescent glasses and ceramics. ZnF2 is also used as a source of zinc in oxygen sensitive applications, and can be used as reagent for producing thin films of Zn metal and ZnO.

pictograms

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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Cao, L.; et al.
Solar Energy Mat. and Solar Cells, 95, 894-894 (2011)
Zhang, Z. G.; et al
International Journal of Hydrogen Energy, 36, 8203-8203 (2011)
Tikhomirov, V. K.; et al.
Applied Physics Letters, 81, 1937-1937 (2002)
Shinsuke Hayashi et al.
The Journal of chemical physics, 129(4), 044313-044313 (2008-08-07)
Highly correlated ab initio calculations have been performed for an accurate determination of the electronic structure and of the spectroscopy of the low lying electronic states of the ZnF system. Using effective core pseudopotentials and aug-cc-pVQZ basis sets for both
Shū Kobayashi et al.
Journal of the American Chemical Society, 124(20), 5640-5641 (2002-05-16)
The catalytic, diastereo- and enantioselective Mannich-type reaction of a hydrazono ester with silyl enol ethers in aqueous media has been successfully achieved with ZnF(2), a chiral diamine ligand, and trifluoromethanesulfonic acid.

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