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Merck
CN

749133

2-(Dodecylthiocarbonothioylthio)propionic acid

97%

Synonym(s):

2-(Dodecylthiocarbonothioylthio)propanoic acid, 2-{[(Dodecylsulfanyl)carbonothioyl]sulfanyl}propanoic acid, DoPAT

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About This Item

Empirical Formula (Hill Notation):
C16H30O2S3
CAS Number:
558484-21-2
Molecular Weight:
350.60
NACRES:
NA.23
PubChem Substance ID:
329765970
UNSPSC Code:
12352100
MDL number:
MFCD22200510

Key Documents

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Product Name

2-(Dodecylthiocarbonothioylthio)propionic acid, 97%

InChI

1S/C16H30O2S3/c1-3-4-5-6-7-8-9-10-11-12-13-20-16(19)21-14(2)15(17)18/h14H,3-13H2,1-2H3,(H,17,18)

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)C(O)=O

InChI key

CFCFZJHCTNKHGJ-UHFFFAOYSA-N

assay

97%

form

powder or crystals

mp

78-82 °C

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate and acrylamide monomers. Chain Transfer Agent (CTA)

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBJ7923V
MKBJ7922V

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Connor R Bilchak et al.
ACS nano (2020-11-21)
Polymer membranes are critical to many sustainability applications that require the size-based separation of gas mixtures. Despite their ubiquity, there is a continuing need to selectively affect the transport of different mixture components while enhancing mechanical strength and hindering aging.
Gordana Siljanovska Petreska et al.
Polymers, 12(6) (2020-06-04)
AB diblock waterborne copolymers made of styrene (St) and 2-ethylhexyl acrylate (2EHA) were synthesized by means of two-step reversible addition fragmentation chain transfer (RAFT) (mini)emulsion polymerization. Monofunctional asymmetric RAFT agent was used to initiate the polymerization. The hard polystyrene "A"
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

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RAFT Agents for Functionalized Polymers

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

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