748188
Bis(2,2,6,6-tetramethylpiperidinyl)zinc, lithium chloride, magnesium chloride complex solution
in THF/toluene
About This Item
form
liquid
composition
Bis(2,2,6,6-tetramethylpiperidinyl)zinc, ~12 wt. %
LiCl, 2-4%
MgCl2, 6-9%
THF/toluene, ca. 90:10 (solvent)
concentration
in THF/toluene
density
0.991 g/mL at 25 °C
General description
Application
- Regioselective zincation of pyridines and related azines to synthesize zincated pyridines and azines.(1)
- Chemoselective direct zincation of arenes and heteroarenes to synthesize polyfunctional aryl and heteroaryl zinc reagents.
- Regioselective zincation of thiazoles to synthesize zincated thiazoles, which readily reacts with various electrophiles to form highly functionalized thiazoles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
5.0 °F
Flash Point(C)
-15 °C
Regulatory Information
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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