Skip to Content

Dear Customer:

The current international situation is complex and volatile, and uncertain tariff policies may potentially impact our product prices. Given these uncertainties, we value your understanding regarding order-related matters.

If you decide to place an order during this period, we reserve the right to adjust the price based on the evolving situation. We understand that market changes may cause inconvenience. We will negotiate with you if there’s a significant price fluctuation due to tariff policy changes before the order’s actual delivery, and in such cases we may adjust or cancel the order as necessary.

For important updates on recent policy changes, please click here for more details.

Merck
CN
All Photos(2)

Key Documents

View All Documentation

747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Synonym(s):

[Ir{dF(CF3)ppy}2(dtbpy)]PF6, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

Sign Into View Organizational & Contract Pricing

Select a Size

100 MG
CN¥2,281.89
1 G
CN¥3,229.83

CN¥2,281.89

Available to ship onApril 16, 2025Details

Request a Bulk Order
All Photos(2)

Select a Size

Change View
100 MG
CN¥2,281.89
1 G
CN¥3,229.83

About This Item

Empirical Formula (Hill Notation):
C42H34F16IrN4P
CAS Number:
870987-63-6
Molecular Weight:
1121.91
MDL number:
MFCD27952556
UNSPSC Code:
12161600
NACRES:
NA.22

CN¥2,281.89

Available to ship onApril 16, 2025Details

Request a Bulk Order

form

solid

Quality Level

100

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.[1][2][3][4][5]It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.[3]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

  • Specification Sheet

    • Choose from one of the most recent versions:

    Certificates of Analysis (COA)

    Lot/Batch Number
    0000432515
    0000432515
    0000428378
    0000428378
    0000408277

    Don't see the Right Version?

    If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

    Search for a COA

    Already Own This Product?

    Find documentation for the products that you have recently purchased in the Document Library.

    Visit the Document Library

    A photochemical strategy for lignin degradation at room temperature.
    Nguyen J D, et al.
    Journal of the American Chemical Society, 136(4), 1218-1221 (2014)
    Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.
    Teegardin K, et al.
    Organic Process Research & Development, 20(7), 1156-1163 (2016)
    Formal Total Synthesis of l-Ossamine via Decarboxylative Functionalization Using Visible-Light-Mediated Photoredox Catalysis in a Flow System.
    Inuki S, et al.
    The Journal of Organic Chemistry, 82(2), 1248-1253 (2017)
    Radical Carbon?Carbon Bond Formations Enabled by Visible Light Active Photocatalysts.
    Wallentin C J, et al.
    Chimia, 66(6), 394-398 (2012)
    Late?Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis.
    DiRocco D A et al.
    Angewandte Chemie (International Edition in English), 53(19), 4802-4806 (2014)

    Related Content

    Stephenson Group – Professor Product Portal

    Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

    Buchwald and non-Buchwald catalysts and ligands for pharma or industrial chemistry applications

    Explore reliable, premium grade catalysis materials for your pharma or industrial project. Specialty chemicals and formulations are available in bulk quantities and volumes from a few grams to multi-metric tons with complete documentation to simplify your leap from development to commercialization.

    Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

    Contact Technical Service