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Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

Name: Dichlorotriphenylphosphine[2-(diphenylphosphino)-<I>N</I>-(2-pyridinylmethyl)ethanamine]ruthenium(II)
Brand: ALDRICH

97%

Synonym(s):

Ru-PNN catalyst

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About This Item

Empirical Formula (Hill Notation):

C₃₈H₃₆C_l2N₂P₂Ru

CAS Number:

1388712-91-1

MDL number:

MFCD26960800

UNSPSC Code:

12161600

PubChem Substance ID:

329765760

NACRES:

NA.22

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

275-295 °C

greener alternative category

Aligned,

SMILES string

Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI

1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

InChI key

JFYJJNHKCBDTMZ-UHFFFAOYSA-L

Related Categories

Greener Alternative Products

Hydrogenation Catalysts

Ruthenium Catalysts

Transition Metal Catalysts

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H302 + H312,H331

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Spasyuk, D.;

Angewandte Chemie (International Edition in English), 2772-2772 (2012)