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Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

Name: Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)
Brand: ALDRICH

97%

Synonym(s):

Ru-SNS catalyst

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About This Item

Empirical Formula (Hill Notation):

C₂₆H₃₄Cl₂NPRuS₂

CAS Number:

1462397-86-9

Molecular Weight:

627.63

MDL number:

MFCD26960799

UNSPSC Code:

12161600

PubChem Substance ID:

329765759

NACRES:

NA.22

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

300-310 °C

greener alternative category

Aligned,

SMILES string

CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI

1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZQGMNGJIEYHKBR-UHFFFAOYSA-L

Related Categories

Greener Alternative Products

Hydrogenation Catalysts

Ruthenium Catalysts

Transition Metal Catalysts

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

Catalyst for the hydrogenation of esters to alcohols.

Other Notes

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H302 + H312,H331

Precautionary Statements

P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Replacing phosphorus with sulfur for the efficient hydrogenation of esters.

Denis Spasyuk et al.

Angewandte Chemie (International ed. in English), 52(9), 2538-2542 (2013-01-29)

Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2)(PPh(3)){HN(C(2)H(4)SEt)(2)}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C=X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling