745855
12-Mercaptododecylphosphonic acid
95%
Synonym(s):
P-(12-Mercaptododecyl)phosphonic acid
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About This Item
Empirical Formula (Hill Notation):
C12H27O3PS
CAS Number:
Molecular Weight:
282.38
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Product Name
12-Mercaptododecylphosphonic acid, 95%
InChI
1S/C12H27O3PS/c13-16(14,15)11-9-7-5-3-1-2-4-6-8-10-12-17/h17H,1-12H2,(H2,13,14,15)
SMILES string
OP(O)(CCCCCCCCCCCCS)=O
InChI key
PVIUMTORLYKRJT-UHFFFAOYSA-N
assay
95%
form
powder
mp
92-96 °C
storage temp.
2-8°C
Quality Level
Related Categories
Application
MDPA based SAM can be coated on TiO2 for potential applications in the extraction of heavy metals. It can also be used in surface modification of a graphene oxide (GO) based active material for the fabrication of a organic field effect transistor (OFET).
Organophosphonic acid self-assembled monolayers (SAMs) for nanoelectronics; solid-state lighting; energy generation and nanocomposites. A mercaptoalkylphosphonate monolayer used to bind gold nanoparticles.
General description
12-Mercaptododecylphosphonic acid (MDPA) is an organophosphonic acid that forms a self-assembled monolayer (SAM). The phosphonic groups tend to react with the metal surfaces that allow the formation of metal-oxygen-phosphonate (M-O-P) bonds that facilitate the surface with mechanical and chemical stability.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
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Self-Assembled Monolayers of 12-Mercaptododecylphosphonic Acid on Titania Particles; Application to the Extraction of Heavy Metals
Antherieu S, et al.
MRS Online Proceedings Library, 847(1), 141-149 (2004)
Peter J O'Brien et al.
Nature materials, 12(2), 118-122 (2012-11-20)
Manipulating interfacial thermal transport is important for many technologies including nanoelectronics, solid-state lighting, energy generation and nanocomposites. Here, we demonstrate the use of a strongly bonding organic nanomolecular monolayer (NML) at model metal/dielectric interfaces to obtain up to a fourfold
Driving forces for the self-assembly of graphene oxide on organic monolayers
Kirschner J, et al.
Nanoscale, 6(19), 11344-11350 (2014)
Phosphonate monolayers functionalized by silver thiolate species as antibacterial nanocoatings on titanium and stainless steel
Amalric J, et al.
Journal of Materials Chemistry, 19(1), 141-149 (2009)
Randall M Stoltenberg et al.
Langmuir : the ACS journal of surfaces and colloids, 27(1), 445-451 (2010-12-08)
Developing orthogonal surface chemistry techniques that perform at the nanoscale is key to achieving precise control over molecular patterning on surfaces. We report the formation and selective functionalization of alumina nanoparticle arrays generated from block copolymer templates. This new material
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