737321
Triphenylbismuth
98% (99.9% trace metals basis)
Synonym(s):
TPB
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About This Item
Linear Formula:
Bi(C6H5)3
CAS Number:
Molecular Weight:
440.29
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
210-033-4
MDL number:
InChI key
ZHXAZZQXWJJBHA-UHFFFAOYSA-N
InChI
1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;
SMILES string
c1ccc(cc1)[Bi](c2ccccc2)c3ccccc3
assay
98% (99.9% trace metals basis)
form
powder or crystals
reaction suitability
core: bismuth
availability
available only in USA
mp
76-81 °C
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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O Anjaneyulu et al.
Dalton transactions (Cambridge, England : 2003), 41(3), 1004-1012 (2011-11-23)
The reaction of triphenylbismuth [BiPh(3)] with several heterocyclic carboxylic acids was explored. Seven crystalline compounds, [PhBi(2-O(2)C-3-(OH)C(5)H(3)N)(2)(2-O(2)C-3-(OH)C(5)H(3)NH)] (5), [(Bi(2-O(2)C-3-(OH)C(5)H(3)N)(4))(C(5)H(5)NH)(C(5)H(5)N)] (7), [PhBi(2-O(2)C-C(4)H(3)N(2))(2)(2-O(2)C-C(4)H(4)N(2))·H(2)O] (8), [PhBi(2-O(2)C-C(9)H(6)N)(2)·H(2)O] (9), [Ph(2)Bi(O(2)C-C(4)H(3)O)] (10), [Ph(2)Bi(O(2)C-C(4)H(3)S)] (11) and [PhBi(O(2)C-C(4)H(3)S)(2)](2) (12), were prepared by simple reactions using BiPh(3) and the corresponding
Stejskal, J.; Leitner, J.J.; Sedmidubsky, D. et al
Journal of Crystal Growth, 210, 587-587 (2000)
S N Abdulghani et al.
Journal of biomaterials science. Polymer edition, 14(11), 1229-1242 (2004-02-11)
Self-curing acrylic bone cements are widely used in the fixation of prosthetic implants in orthopaedic surgery. Commercial bone cements are rendered radiopaque by the addition of heavy metal salts of barium and zirconia. The addition of barium sulphate adversely affects
P A Mattie et al.
Journal of prosthodontics : official journal of the American College of Prosthodontists, 3(4), 213-218 (1994-12-01)
Current prosthetic acrylic resins are radiolucent and cannot be imaged using standard radiographic techniques. If accidentally impacted or ingested, delays in localizing or removing the foreign body may be life-threatening. The purpose of this study was to evaluate the influence
Brad H Jones et al.
Macromolecular rapid communications, 42(4), e2000571-e2000571 (2020-12-11)
This communication describes a novel series of linear and crosslinked polyurethanes (PUs) and their selective depolymerization under mild conditions. Two unique polyols are synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis (RCM) to five- and six-membered
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