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Merck
CN

727490

Azidobenzene solution

~0.5 M in tert-butyl methyl ether

Synonym(s):

Phenyl azide solution

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About This Item

Empirical Formula (Hill Notation):
C6H5N3
CAS Number:
Molecular Weight:
119.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
742248
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Product Name

Azidobenzene solution, ~0.5 M in tert-butyl methyl ether

InChI

1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H

SMILES string

[N-]=[N+]=Nc1ccccc1

InChI key

CTRLRINCMYICJO-UHFFFAOYSA-N

assay

≥95.0% (HPLC)

form

liquid

concentration

~0.5 M in tert-butyl methyl ether

impurities

≤2.0% water

functional group

azide

storage temp.

−20°C

Quality Level

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signalword

Danger

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F

flash_point_c

4 °C

Regulatory Information

危险化学品
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Pascal Viel et al.
Langmuir : the ACS journal of surfaces and colloids, 29(6), 2075-2082 (2013-01-16)
Covalent immobilization of unmodified biological materials as proteins has been performed through a one-step and soft method. This process is based on a polyazidophenylene layer derived from the electroreduction of the parent salt 4-azidobenzenediazonium tetrafluoborate on gold substrates. The wavelength
C Malaveille et al.
Cancer research, 42(4), 1446-1453 (1982-04-01)
3-Methyl-1-phenyltriazene and a series of ring-substituted derivatives (4-methylphenyl, 4-chlorophenyl, and 2,4,6-trichlorophenyl), structurally related benzenediazonium fluoborates and phenyl azides, as well as the recently isolated [1-methyl-3-(2,4,6-trichlorophenyl)-2-triazeno]methyl-beta-D-glucopyranoside uronic acid, were studied for their mutagenic activity in Salmonella typhimurium strains. Of these compounds
Laëtitia Renaudie et al.
Biomacromolecules, 8(2), 679-685 (2007-02-13)
Grafting of a new carbohydrate UV-reactive molecule, an azidophenyl lactamine (AzPhLac), was achieved on fibers of three different diameters: 12, 18, and 32 microm. Adsorption of AzPhLac on fibers was obtained by using the dip-coating method in solution. The effect
Emily J Borda et al.
Nucleic acids research, 33(3), 1058-1068 (2005-02-22)
We have used photo-crosslinking to investigate the structure and dynamics of four-way junction hairpin ribozyme constructs. Four phenylazide photo-crosslinkers were coupled to 2'-NH2-modified U+2 in the substrate and irradiated at different Mg2+ concentrations and temperatures. Consistent with the role of
Luís M T Frija et al.
The journal of physical chemistry. A, 111(15), 2879-2888 (2007-03-29)
A combined matrix isolation FT-IR and theoretical DFT(B3LYP)/6-311++G(d,p) study of the molecular structure and photochemistry of 5-ethoxy-1-phenyl-1H-tetrazole (5EPT) was performed. A new method of synthesis of the compound is described. Calculations show three minima, very close in energy and separated

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