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Merck
CN

723207

Dipentaerythritol hexakis(2-bromoisobutyrate)

Synonym(s):

6f-BiB, Hexafunctional 2-bromoisobutyrate, Hexafunctional initiator

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About This Item

Empirical Formula (Hill Notation):
C34H52Br6O13
CAS Number:
840507-47-3
Molecular Weight:
1148.19
UNSPSC Code:
12162002
PubChem Substance ID:
329763986
MDL number:
MFCD16621495

Key Documents

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InChI

1S/C34H52Br6O13/c1-27(2,35)21(41)48-15-33(16-49-22(42)28(3,4)36,17-50-23(43)29(5,6)37)13-47-14-34(18-51-24(44)30(7,8)38,19-52-25(45)31(9,10)39)20-53-26(46)32(11,12)40/h13-20H2,1-12H3

SMILES string

CC(C)(Br)C(=O)OCC(COCC(COC(=O)C(C)(C)Br)(COC(=O)C(C)(C)Br)COC(=O)C(C)(C)Br)(COC(=O)C(C)(C)Br)COC(=O)C(C)(C)Br

InChI key

QZIIQQIGYHRTNR-UHFFFAOYSA-N

mp

124-134 °C

Application

ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers
Atom Transfer Radical Polymerization (ATRP) initiator for the creation of hexafunctional polymers.
Polymerization will occur at six sites creating a six-arm star polymer.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN2631V
MKBF7297

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Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)

Articles

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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