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723150

Sigma-Aldrich

2-Hydroxyethyl 2-bromoisobutyrate

95%

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Synonym(s):
ATRP hydroxy initiator, HEBIB, HO-BriBu
Empirical Formula (Hill Notation):
C6H11BrO3
CAS Number:
Molecular Weight:
211.05
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

95%

form

liquid

refractive index

n20/D 1.476

density

1.456 g/mL at 25 °C

SMILES string

CC(C)(Br)C(=O)OCCO

InChI

1S/C6H11BrO3/c1-6(2,7)5(9)10-4-3-8/h8H,3-4H2,1-2H3

InChI key

MHXMVFDLNGKBSR-UHFFFAOYSA-N

Related Categories

Application

Atom Transfer Radical Polymerization (ATRP) initiator for the creation of hydroxy functionalized telechelic polymers. Can be used to modify carboxylate- or isocyanate- modified surfaces, particles or biomolecules.

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Description
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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Abhispa Sahu et al.
Ultrasonics sonochemistry, 67, 105163-105163 (2020-05-18)
This paper reports on sonochemically catalyzed atom transfer radical polymerization (SONO-ATRP) polyelectrolyte synthesis and chain-end functionalization to single-walled carbon nanotubes (SWCNT). This all aqueous process is kinetically facile without use of initiator, or reducing agents and with very low concentrations
Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
Jingli Chen et al.
Theranostics, 7(17), 4149-4167 (2017-11-22)
Currently unsatisfactory treatment of myocardial infarction (MI) is due to the unbridled inflammation and the delayed diagnosis at the early stage. To address these problems, firstly, phosphatidylserine (PS) was used to modulate the phenotypes of macrophages (MΦ) and resolve the
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)

Articles

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Protocols

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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