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Merck
CN

723126

Bis(dodecylsulfanylthiocarbonyl) disulfide

≥95%

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About This Item

Empirical Formula (Hill Notation):
C26H50S6
CAS Number:
Molecular Weight:
555.07
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

Bis(dodecylsulfanylthiocarbonyl) disulfide, ≥95%

InChI

1S/C26H50S6/c1-3-5-7-9-11-13-15-17-19-21-23-29-25(27)31-32-26(28)30-24-22-20-18-16-14-12-10-8-6-4-2/h3-24H2,1-2H3

SMILES string

CCCCCCCCCCCCSC(=S)SSC(=S)SCCCCCCCCCCCC

InChI key

UUNRYKCXJSDLRD-UHFFFAOYSA-N

assay

≥95%

form

solid

mp

30-35 °C

storage temp.

−20°C

Quality Level

Application

Precursor for the synthesis of RAFT agents for controlled radical polymerization.

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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