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Safety Information

71915

Sigma-Aldrich

Sodium 1-propanethiolate

technical, ≥95% (RT)

Synonym(s):

1-Propanethiol sodium salt

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About This Item

Linear Formula:
CH3CH2CH2SNa
CAS Number:
Molecular Weight:
98.14
Beilstein:
3556024
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

grade

technical

Quality Level

Assay

≥95% (RT)

form

crystals

SMILES string

CCCS[Na]

InChI

1S/C3H8S.Na/c1-2-3-4;/h4H,2-3H2,1H3;/q;+1/p-1

InChI key

XVSFHIIADLZQJP-UHFFFAOYSA-M

Other Notes

Salts of alkanethiols are versatile intermediates for the synthesis of various thiol esters and thio ethers. In contrast to the stenchy gaseous or liquid thiols, the salts are easy to handle solids.; Alkanethiolates are strong nucleophiles and thus efficient reagents for SN2 type dealkylations of hindered esters and lactones; Dealkylation of aryl methyl ethers

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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G.I. Feutrill et al.
Tetrahedron Letters, 1327-1327 (1970)
P.A. Bartlett et al.
Tetrahedron Letters, 4459-4459 (1970)
L. Testaferri et al.
Synthesis, 751-751 (1983)
W.R. Vaughan et al.
The Journal of Organic Chemistry, 27, 739-739 (1962)
[Use of a nuclear activation method in the study of toxicokinetics of chemical substances].
A A Aleksandrov et al.
Gigiena i sanitariia, (5)(5), 88-90 (1991-05-01)

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