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718165

Sigma-Aldrich

Trioctylphosphine

97%

Synonym(s):

TOP, P(Oct)3

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100 ML
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500 ML
¥9,650.31
2 L
¥22,978.06

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Available to ship on2025年4月07日Details

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100 ML
¥2,974.67
500 ML
¥9,650.31
2 L
¥22,978.06

About This Item

Linear Formula:
[CH3(CH2)7]3P
CAS Number:
4731-53-7
Molecular Weight:
370.64
Beilstein:
1776995
EC Number:
225-234-2
MDL number:
MFCD00015298
UNSPSC Code:
12352001
PubChem Substance ID:
329763556
NACRES:
NA.22

¥2,974.67

Available to ship on2025年4月07日Details

Request a Bulk Order

Quality Level

100

Assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

density

0.831 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

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General description

Trioctylphosphine serves as a phosphorus source and used in the synthesis of metal nanoparticles.[1]

Application

Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides.[2] It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.[3]

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

296.6 °F - closed cup

Flash Point(C)

147 °C - closed cup

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    Lot/Batch Number
    MKCX3408
    MKCT1692
    MKCP6805
    SHBM3450
    SHBL9126

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    Trioctylphosphine as both solvent and stabilizer to synthesize CdS nanorods.
    Chen S, et al.
    Nanoscale Research Letters, 4(10), 1159-1159 (2009)
    Trioctylphosphine: a general phosphorus source for the low-temperature conversion of metals into metal phosphides.
    Henkes AE & Schaak RE.
    Chemistry of Materials, 19(17), 4234-4242 (2007)
    Palladium (ii)-complexes of bi-and tri-dentate phosphine ligands: precursor for palladium--phosphorous nanoparticles and activity towards Suzuki--Miyaura coupling
    Rao GK, et al.
    New. J. Chem., 47, 4218-4227 (2023)
    Tilman Läppchen et al.
    EJNMMI physics, 7(1), 22-22 (2020-04-24)
    For multicenter clinical studies, PET/CT and SPECT/CT scanners need to be validated to ensure comparability between various scanner types and brands. This validation is usually performed using hollow phantoms filled with radioactive liquids. In recent years, 3D printing technology has
    Kimberly H Hartstein et al.
    ACS nano, 11(10), 10430-10438 (2017-09-16)
    We examine the effects of CdS shell growth on photochemical reduction of colloidal CdSe quantum dots (QDs) and describe the spectroscopic properties of the resulting n-type CdSe/CdS QDs. CdS shell growth greatly slows electron trapping. Because of this improvement, complete
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