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Sigma-Aldrich

Bis(dicyclohexylphosphinophenyl) ether

97%

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Synonym(s):
(Oxydi-2,1-phenylene)bis[dicyclohexyl] phosphine
Empirical Formula (Hill Notation):
C36H52OP2
CAS Number:
Molecular Weight:
562.75
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

140-146 °C

functional group

phosphine

SMILES string

C1CCC(CC1)P(C2CCCCC2)c3ccccc3Oc4ccccc4P(C5CCCCC5)C6CCCCC6

InChI

1S/C36H52OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h13-16,25-32H,1-12,17-24H2

InChI key

HPFGZHCWLVSVKJ-UHFFFAOYSA-N

Application

Catalyst for diastereoselective intramolecular N-arylation intermolecular carboamination

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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