714836
Iodine monochloride solution
1 M in acetic acid
Synonym(s):
Chloroiodide solution, Wijs solution
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About This Item
Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587194
Product Name
Iodine monochloride solution, 1 M in acetic acid
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
SMILES string
ClI
InChI
1S/ClI/c1-2
form
solution
concentration
1 M in acetic acid
density
1.143 g/mL at 25 °C
Quality Level
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Application
Iodine monochloride can be used:
- As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
- In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.
General description
Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.1 °F
flash_point_c
40.6 °C
Regulatory Information
危险化学品
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Steric effects on the sydnones reactivity. New sydnones and pyrazoles
Dumitracscu F, et al.
ARKIVOC (Gainesville, FL, United States), 2(26), 80-86 (2002)
Iodine monochloride
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride
Suryakiran N, et al.
Tetrahedron Letters, 47(26), 4319-4323 (2006)
F Ibrahim et al.
Journal of pharmaceutical and biomedical analysis, 9(2), 101-107 (1991-01-01)
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