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713074

Sigma-Aldrich

1-Butyl-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide

97%

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Synonym(s):
PP14TFSI, [Bmpip][NTf2]
Empirical Formula (Hill Notation):
C12H22F6N2O4S2
CAS Number:
Molecular Weight:
436.43
Beilstein:
10137193
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

liquid

impurities

≤0.2% water

SMILES string

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.C[N+]1(CCCC)CCCCC1

InChI

1S/C10H22N.C2F6NO4S2/c1-3-4-8-11(2)9-6-5-7-10-11;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-10H2,1-2H3;/q+1;-1

InChI key

ZDMWZUAOSLBMEY-UHFFFAOYSA-N

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Application

1-Butyl-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide is an ionic liquid that can be used:
  • As an electrolyte in ionic liquid dual ion battery and dual-graphite battery.
  • As a model ionic liquid in the study of ionic effect on the desulfurization of fuels.
  • In the study of the activity coefficient of different solutes at infinite dilution.

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Experimental and theoretical study on infinite dilution activity coefficients of various solutes in piperidinium ionic liquids
Paduszynski K and Domanska U
The Journal of Chemical Thermodynamics, 60, 169-178 (2013)
A dual-graphite battery with pure 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide as the electrolyte
Wang A, et al.
Energy Technology, 6(11), 2172-2178 (2018)
Effect of the cation and anion of the ionic liquid on desulfurization of model fuels.
Domanska U and Wlazlo M.
Fuel: The Science and Technology of Fuel and Energy, 134, 114-125 (2014)
An excellent rechargeable PP 14 TFSI ionic liquid dual-ion battery
Fan J, et al.
Chemical Communications (Cambridge, England), 53(51), 6891-6894 (2017)

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