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1-Ethyl-3-methylimidazolium iodide

Name: 1-Ethyl-3-methylimidazolium iodide
Brand: ALDRICH

97%

Synonym(s):

EMIMI

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About This Item

Empirical Formula (Hill Notation):

C₆H₁₁IN₂

CAS Number:

35935-34-3

Molecular Weight:

238.07

Beilstein:

5160333

MDL number:

MFCD03701101

UNSPSC Code:

12352100

PubChem Substance ID:

329763170

NACRES:

NA.22

Quality Level

100

Assay

≥96.5% (HPLC)
97%

form

powder

impurities

≤0.5% water

SMILES string

[I-].CCn1cc[n+](C)c1

InChI

1S/C6H11N2.HI/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1

InChI key

IKQCDTXBZKMPBB-UHFFFAOYSA-M

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General description

1-Ethyl-3-methylimidazolium iodide is an ionic liquid that can be prepared by reacting methylimidazole with iodoethane. The addition of EMImI to 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF₄)_, increase its capacitance while developing electric double-layer capacitors (EDLCs) based on EMImBF₄.

Application

EMImI reacts with aluminum chloride to form 1-ethyl-3-methylimidazolium halogenoaluminate ionic liquid, [emim]I–(AlCl₃)_x, which is an excellent solvent for Friedel–Crafts acylation of ferrocene.

Pictograms

GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H318,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P301 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as reaction media for the acylative cleavage of ethers

Green, Laine, Ivan Hemeon, and Robert D. Singer

Tetrahedron Letters, 41.9, 1343-1346 (2000)

Electrochemical characteristics pyrolytic graphite| mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide interface

Siinor, Liis, et al.

Journal of Electroanalytical Chemistry, 719, 133-137 (2014)

1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as solvents for Friedel-Crafts acylation reactions of ferrocene.

MacLean B and Singer R.

J. Chem. Soc., Dalton Trans., 1, 63-66 (1999)

The electrochemical characteristics of the mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide

Siimenson, Carolin, et al.

Journal of Electroanalytical Chemistry, 730, 59-64 (2014)

Electrochemical study of copper in a basic 1-ethyl-3-methylimidazolium tetrafluoroborate room temperature molten salt

Chen, Po-Yu, and I-Wen Sun

Electrochimica Acta, 45.3, 441-450 (1999)

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