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71208

Sigma-Aldrich

Sodium ethanethiolate

technical, ~90% (RT)

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Synonym(s):
Ethanethiol sodium salt, Ethyl mercaptan sodium salt
Linear Formula:
CH3CH2SNa
CAS Number:
Molecular Weight:
84.12
Beilstein:
3593647
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical

Quality Level

Assay

~90% (RT)

form

crystals

SMILES string

CCS[Na]

InChI

1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1

InChI key

QJDUDPQVDAASMV-UHFFFAOYSA-M

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Application

Sodium ethanethiolate is a reagent generally used to synthesize various thioethers. It can be employed as a ligand in the preparation of organometallic complexes. It is also used in the synthesis of thiolated amino-alcohols.

Other Notes

Alkanethiolates are efficient reagents for SN2 dealkylation of esters and aryl ethers

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Novel thiolated amino-alcohols as chiral ligands for copper-catalyzed asymmetric nitro-aldol reactions.
Mansawat, Woraluk et al.
Tetrahedron Letters, 48(24), 4235-4238 (2007)
G.I. Feutrill et al.
Tetrahedron Letters, 1327-1327 (1970)
P.A. Bartlett et al.
Tetrahedron Letters, 4459-4459 (1970)
Kojyl thioether derivatives having both tyrosinase inhibitory and anti-inflammatory properties.
Rho, Ho Sik et al.
Bioorganic & Medicinal Chemistry Letters, 20(22), 6569-6571 (2010)
Mononuclear Ni (III) Complexes [NiIII (L)(P (C6H3-3-SiMe3-2-S) 3)] 0/1-(L= Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases.
Lee, Chien-Ming et al.
Inorganic Chemistry, 45(26), 10895-10904 (2006)

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