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710873

Sigma-Aldrich

Methyllithium solution

greener alternative

3% in 2-Methyltetrahydrofuran/cumene

Synonym(s):

Lithium methanide, MeLi

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About This Item

Empirical Formula (Hill Notation):
CH3Li
CAS Number:
917-54-4
Molecular Weight:
21.98
Beilstein:
3587162
MDL number:
MFCD00008253
UNSPSC Code:
12352103
PubChem Substance ID:
329763017

form

liquid

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

concentration

3% in 2-Methyltetrahydrofuran/cumene

density

0.860 g/mL at 25 °C

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

[Li]C

InChI

1S/CH3.Li/h1H3;

InChI key

DVSDBMFJEQPWNO-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Organolithium in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

19.4 °F

Flash Point(C)

-7 °C

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBF3992V
STBD5736V
SHBD5291V
STBD2347V
STBB6781V

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Erik Selander et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(20), 6395-6400 (2015-04-29)
Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing to perceive their surroundings. However, few of the signaling molecules involved in interactions

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