708704
RuCl[(R,R)-FsDPEN](p-cymene)
90%
Synonym(s):
[N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-2,3,4,5,6-pentafluorobenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
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About This Item
Product Name
RuCl[(R,R)-FsDPEN](p-cymene), 90%
InChI
1S/C20H14F5N2O2S.C10H14.ClH.Ru/c21-13-14(22)16(24)20(17(25)15(13)23)30(28,29)27-19(12-9-5-2-6-10-12)18(26)11-7-3-1-4-8-11;1-8(2)10-6-4-9(3)5-7-10;;/h1-10,18-19H,26H2;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t18-,19-;;;/m1.../s1
SMILES string
CC(C)c1ccc(C)cc1.N[C@@H]([C@H](N([Ru]Cl)S(=O)(=O)c2c(F)c(F)c(F)c(F)c2F)c3ccccc3)c4ccccc4
InChI key
UWFMZLATRGEOIW-ZJPTYAPPSA-M
assay
90%
form
powder
optical activity
[α]25/D −16°, c = 0.1 in chloroform
mp
238-244 °C
functional group
amine
fluoro
phenyl
storage temp.
2-8°C
Quality Level
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Legal Information
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
>212.0 °F - open cup
flash_point_c
> 100 °C - open cup
ppe
Eyeshields, Gloves, type N95 (US)
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Articles
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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