708496
Acetyl chloride solution
1 M in methylene chloride
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About This Item
Empirical Formula (Hill Notation):
C2H3ClO
CAS Number:
Molecular Weight:
78.50
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Form:
liquid
Product Name
Acetyl chloride solution, 1 M in methylene chloride
InChI
1S/C2H3ClO/c1-2(3)4/h1H3
SMILES string
CC(Cl)=O
InChI key
WETWJCDKMRHUPV-UHFFFAOYSA-N
form
liquid
concentration
1 M in methylene chloride
refractive index
n20/D 1.423
density
1.294 g/mL at 25 °C
functional group
acyl chloride
Quality Level
Application
Acetyl chloride (AcCl) can be used as:
- An acylating reagent to prepare useful key intermediates in organic synthesis.
- A reagent to convert oxathioacetals and dithioacetals into corresponding carbonyl compounds in the presence of sodium nitrite.
- An activating or acylating reagent in solid-phase organic synthesis.
- A reagent to prepare various alkyl and aryl tetrahydropyranyl ethers from corresponding alcohols.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
wgk
WGK 2
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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New phenylfluorenyl based linkers for solid phase synthesis
Bleicher KH, et al.
Tetrahedron Letters, 41(47), 9037-9042 (2000)
Selective synthesis of spirooxindoles via a two-step reaction of N-phenacylpyridinium bromide, 1, 3-indanedione and N-alkylisations
Sun J, et al.
Organic & Biomolecular Chemistry, 17(16), 3978-3983 (2019)
Solid phase synthesis of styrylquinazolinones
Theoclitou M-E, et al.
Tetrahedron Letters, 41(13), 2051-2054 (2000)
Acetyl chloride-mediated mild and chemoselective attachment and removal of tetrahydropyranyl (THP) group
Yeom C-E, et al.
Bulletin of the Korean Chemical Society,, 28(1), 103-107 (2007)
A highly efficient procedure for regeneration of carbonyl groups from their corresponding oxathioacetals and dithioacetals using sodium nitrite and acetyl chloride in dichloromethane
Khan AT, et al.
Synlett, 2003(03), 0377-0381 (2003)
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