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Sigma-Aldrich

Small gap fullerenes

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UNSPSC Code:
12352103
NACRES:
NA.23

form

granular

mol wt

average Mw ~1,000

composition

fullerenes, ≥80%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

>400 °C

solubility

organic solvents: soluble

greener alternative category

Enabling,

SMILES string

C=1=C2c3c4C=1c5c6c7c8c9c%10c%11c%12c%13C%14=[C]%10=C%15c%16c%17c%14c%18c%13c%19c%20c%12c%21c%11c(c%22c%23c%24c(C2=[C]7%15%22)c%25c3c%26c%27c4c%28c5c(c6%16)c%29c%17c%30c%18c%31c%19c%32c%20c(c%21%23)c%33c%24c%34c%25c%26c%35c%36c%27c%28c%29c%37c%30c%31c%38c%32c%33c%34c%35c%38c%36%37)c89

General description

Insoluble small gap fullerenes can be extracted into organic solvents by simple chemical redox process.
Small gap fullerenes are higher order fullerenes with low HOMO − LUMO gaps. These allotropes of carbon are also known as metallofullerenes. They are kinetically unstable and are considered as insoluble small band gap structures. They can be extracted into organic solvents by chemical redox processes.
Small gap fullerenes, also known as giant fullerenes, possess small energy differences between the valence band and the conduction band or between the filled and unfilled energy states of individual fullerene molecules.
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Application

Small gap fullerenes can be used as doping agents on polyaniline (PANI) for organic electronics applications.

Legal Information

Product of TDA Research, Inc. and US Patents 6,517,799 and 6,303,016.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319,H335

Hazard Classifications

Eye Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Chemical redox recovery of giant, small-gap and other fullerenes
Raebiger JW, et al.
Carbon, 49(1), 37-46 (2011)
Optical, structural and electrical properties of polyaniline systems doped with C60 and small gap C60 fullerenes
Politakos N, et al.
Materials Chemistry and Physics, 142(1), 387-394 (2013)
Chemical redox recovery of giant, small-gap and other fullerenes
Raebiger, J.W.; Alford, J.M.; Bolskar, R.D.; Diener, M.D.
Carbon, 49, 37-46 (2011)
Small-bandgap endohedral metallofullerenes in high yield and purity.
Stevenson S, et al.
Nature, 401(6748), 55-55 (1999)
Isolation and properties of small-bandgap fullerenes.
Diener MD and Alford JM
Nature, 393(6686), 668-668 (1998)

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