Skip to Content

很抱歉，目前系统维护中。在此期间，网站下单功能无法使用。给您带来不便，深表歉意。如需其他帮助，请联系客户联络中心：400 620 3333。

Merck
CN
All Photos(1)

Key Documents

View All Documentation

703907

Sigma-Aldrich

RuCl(p-cymene)[(R,R)-Ts-DPEN]

Synonym(s):

[N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium

Sign Into View Organizational & Contract Pricing

Select a Size

100 ML
CN¥594.19
500 ML
CN¥849.08
1 L
CN¥1,250.63

CN¥594.19

Estimated to ship onApril 07, 2025Details

Request a Bulk Order
All Photos(1)

Select a Size

Change View
100 ML
CN¥594.19
500 ML
CN¥849.08
1 L
CN¥1,250.63

About This Item

Empirical Formula (Hill Notation):
C31H35ClN2O2RuS
CAS Number:
192139-92-7
Molecular Weight:
636.21
MDL number:
MFCD10567385
UNSPSC Code:
12352116
PubChem Substance ID:
329762075
NACRES:
NA.22

CN¥594.19

Estimated to ship onApril 07, 2025Details

Request a Bulk Order

form

powder

optical activity

[α]20/D −116°, c = 0.1 in chloroform

mp

215 °C

functional group

amine
phenyl

storage temp.

2-8°C

SMILES string

CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChI key

AZFNGPAYDKGCRB-AGEKDOICSA-M

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
48900W0625861375
May-Grünwald solution

63590

May-Grünwald solution

Giemsa Stain, Modified Solution (for the staining (of cellular blood components and blood parasites))

48900

Giemsa Stain, Modified Solution

Wright stain suitable for blood stain

W0625

Wright stain

Wright stain certified by the BSC

861375

Wright stain

suitability

Chlamydia spp., Plasmodium spp., bacteria, spirochetes, Histoplasma spp., protozoa, Trichomonas spp.

suitability

Chlamydia spp., Histoplasma spp., Plasmodium spp., Trichomonas spp., bacteria, protozoa, spirochetes

suitability

-

suitability

-

grade

for the staining of blood constituents

grade

-

grade

-

grade

certified by the Biological Stain Commission

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

density

0.80 g/mL at 20 °C

density

-

density

-

density

-

impurities

methanol

impurities

-

impurities

-

impurities

-

General description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.[1]

Application

Takasago Ligands and Complexes for Asymmetric Reactions
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
  • Quinolines
  • N-Alkyl ketimines
  • Antitumor and antiproliferative derivatives of natural products isolated from bacteria
  • Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves
  • Specification Sheet

    • Choose from one of the most recent versions:

    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCS8197
    MKCM4557
    MKCL9456
    MKCJ9480
    MKCG8576

    Don't see the Right Version?

    If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

    Search for a COA

    Already Own This Product?

    Find documentation for the products that you have recently purchased in the Document Library.

    Visit the Document Library

    Carbonyl compounds: still central to organic synthesis
    Aldrichimica Acta, 41(4) (2008)

    Articles

    Takasago Ligands

    Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

    Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

    Contact Technical Service