701017
2-Furanylboronic acid MIDA ester
97%
Synonym(s):
2-(Furan-2-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione, 2-Furanboronic acid MIDA ester
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About This Item
Empirical Formula (Hill Notation):
C9H10BNO5
CAS Number:
Molecular Weight:
222.99
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
InChI
1S/C9H10BNO5/c1-11-5-8(12)15-10(16-9(13)6-11)7-3-2-4-14-7/h2-4H,5-6H2,1H3
SMILES string
CN1CC(=O)OB(OC(=O)C1)c2ccco2
InChI key
QNZYBMSGFWTQOS-UHFFFAOYSA-N
assay
97%
form
powder
mp
130-135 °C
Application
- Reactant for slow-release cross-coupling reactions
MIDA boronates as stable boronic acid surrogates for classically challenging cross-couplings
Suzuki Cross-Coupling with MIDA Boronates
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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David M Knapp et al.
Journal of the American Chemical Society, 131(20), 6961-6963 (2009-05-02)
Many boronic acids, including 2-heterocyclic, vinyl, and cyclopropyl derivatives, are inherently unstable, which can limit their benchtop storage and/or efficient cross-coupling. We herein report the first general solution to this problem: in situ slow release of unstable boronic acids from
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