698474
Bis(4-methoxyphenyl)chlorophosphine
95%
Synonym(s):
P,P-Bis(4-methoxyphenyl)phosphinous chloride
About This Item
Assay
95%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
62-66 °C
functional group
phosphine
SMILES string
COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI
1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChI key
YTFQUBRFOJIJOZ-UHFFFAOYSA-N
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Application
- Allylic substitution
- Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
- Hydrogenation
- Intramolecular α-arylation of aldehydes
Reactant for:
- Alcoholysis of phosphane-boranes
- Probing hemilabile sites of Bis(phosphine) monoxide ligands
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Information
Certificates of Analysis (COA)
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