Skip to Content
Merck
CN
All Photos(1)

Key Documents

Safety Information

698237

Sigma-Aldrich

Bis(4-trifluoromethylphenyl)phosphine

97%

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C14H9F6P
CAS Number:
Molecular Weight:
322.19
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:

Quality Level

Assay

97%

form

liquid

reaction suitability

reagent type: ligand

refractive index

n20/D 1.512

density

1.317 g/mL at 25 °C

functional group

phosphine

SMILES string

FC(F)(F)c1ccc(Pc2ccc(cc2)C(F)(F)F)cc1

InChI

1S/C14H9F6P/c15-13(16,17)9-1-5-11(6-2-9)21-12-7-3-10(4-8-12)14(18,19)20/h1-8,21H

InChI key

LLJITAAISCMRAR-UHFFFAOYSA-N

Application

Reactant for:
  • Preparation of iron(II) chiral diimine diphosphine complexes as catalysts for asymmetric transfer hydrogenation of ketones
  • Enantioselective decarboxylative allylation and ring-closing metathesis

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 4 - Eye Dam. 1

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service