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Safety Information

693251

Sigma-Aldrich

RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]

Synonym(s):

Dichloro[(S)-(−)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl][(1S,2S)-(−)-1,2-diphenylethylenediamine]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C66H64Cl2N2P2Ru
CAS Number:
220114-03-4
Molecular Weight:
1119.15
MDL number:
MFCD09753030
UNSPSC Code:
12352005
PubChem Substance ID:
329761577
NACRES:
NA.22

form

powder

functional group

amine
phenyl
phosphine

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.N[C@H]([C@@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.0.../s1

InChI key

HYMSONXJNGZZBM-LISIALKWSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCF0629
MKBH9739
05725LH

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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