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693189

Sigma-Aldrich

(S)-Ru(OAc)2(BINAP)

Synonym(s):

Diacetato[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C48H38O4P2Ru
CAS Number:
261948-85-0
Molecular Weight:
841.83
MDL number:
MFCD09753020
UNSPSC Code:
12352005
PubChem Substance ID:
329761570
NACRES:
NA.22

form

powder

functional group

phosphine

storage temp.

2-8°C

InChI

1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

NMLZYEWNUCRSRJ-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
  • Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
  • Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
  • Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
  • Asymmetric reduction of (nitro)(phenyl)propene
  • Asymmetric synthesis of chiral d-lactones via hydrogenation
  • Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBT6923V
MKCG3154
MKBZ3487V
MKBW2574V
MKBQ5074V

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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