Skip to Content
Merck
CN
All Photos(1)

Documents

693189

Sigma-Aldrich

(S)-Ru(OAc)2(BINAP)

Sign Into View Organizational & Contract Pricing
All Photos(1)
Synonym(s):
Diacetato[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II)
Empirical Formula (Hill Notation):
C48H38O4P2Ru
CAS Number:
261948-85-0
Molecular Weight:
841.83
MDL number:
MFCD09753020
UNSPSC Code:
12352005
PubChem Substance ID:
329761570
NACRES:
NA.22

form

powder

storage temp.

2-8°C

InChI

1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

NMLZYEWNUCRSRJ-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
  • Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
  • Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
  • Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
  • Asymmetric reduction of (nitro)(phenyl)propene
  • Asymmetric synthesis of chiral d-lactones via hydrogenation
  • Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene

Legal Information

Sold in collaboration with Takasago for research purposes only.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service