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Merck
CN

688614

Basolite® C 300

greener alternative

produced by BASF

Synonym(s):

Copper benzene-1,3,5-tricarboxylate, Cu-BTC MOF, HKUST-1

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About This Item

Empirical Formula (Hill Notation):
C18H6Cu3O12
Molecular Weight:
604.87
NACRES:
NA.23
PubChem Substance ID:
329761179
UNSPSC Code:
26111700
MDL number:
MFCD10567003

Key Documents

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Product Name

Basolite® C 300, produced by BASF

InChI

1S/2C9H6O6.3Cu/c2*10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;;;/h2*1-3H,(H,10,11)(H,12,13)(H,14,15);;;/q;;3*+2/p-6

SMILES string

O=C(O[Cu]OC(=O)c1cc2cc(c1)C(=O)O[Cu]OC2=O)c3cc4cc(c3)C(=O)O[Cu]OC4=O

InChI key

NOSIKKRVQUQXEJ-UHFFFAOYSA-H

form

solid

reaction suitability

reagent type: catalyst
core: copper

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1500-2100 m2/g

particle size distribution

15.96 μm (D50)

bulk density

0.35 g/cm3

greener alternative category

, Enabling

Quality Level

100

Application

Basolite®C 300 can be used in the adsorption of carbon dioxide, carbon monoxide, and liquid absorption of dibenzothiopene.
Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separations

General description

Basolite®C 300 is a metal organic framework (MOF). It is a crystallized hybrid porous solid built up from inorganic subunits, which are connected to organic linkers such as carboxylates or phosphonates. It is a commercialized sorbent that has the structure of HKUST-1.
HKUST-1 is also known as MOF-199, Cu-BTC and Basolite(TM) C300. HKUST-1 is a blue cubic crystal of copper based ultramicroporous metal framework (MOF). It is prepared by solvothermal method. It could have a surface area of nearly 2200 m2/g2.
MOF (metal organic framework)
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Other Notes

can be reactivated at 200°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ0231
BCCG1834
BCCC1256
BCBZ6293
BCBW8681

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Ayanjeet Ghosh et al.
The journal of physical chemistry letters, 8(21), 5325-5330 (2017-10-13)
We report here the first mesoscale characterization of solvent environments in the metal-organic framework (MOF) Cu
Nak Cheon Jeong et al.
Journal of the American Chemical Society, 134(1), 51-54 (2011-12-14)
HKUST-1, a metal-organic framework (MOF) material containing Cu(II)-paddlewheel-type nodes and 1,3,5-benzenetricarboxylate struts, features accessible Cu(II) sites to which solvent or other desired molecules can be intentionally coordinated. As part of a broader investigation of ionic conductivity in MOFs, we unexpectedly
CO as an IR probe molecule for characterization of copper ions in a basolite C300 MOF sample
Drenchev N, et al.
Physical Chemistry Chemical Physics, 12(24), 6423-6427 (2010)
Yang, H.; et al.
Microporous Mater., 143, 37-45 (2011)
Heba Ahmed et al.
Nature communications, 10(1), 2282-2282 (2019-05-28)
The high surface area and porosity, and limitless compound and network combinations between the metal ions and organic ligands making up metal-organic frameworks (MOFs) offer tremendous opportunities for their use in many applications. While numerous methods have been proposed for
View All Related Papers

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Metal-Organic Frameworks in Energy

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金属有机框架MOF_光伏和太阳能电池-默克生命科学

金属有机骨架（MOF）是一类相对较新的多孔晶体材料，具有广泛的应用范围。MOF由充当接合处的金属离子或簇组成，并由多向有机配体所结合，而其在网络结构中作为接头。

可持续能源技术中的金属有机骨架

金属有机骨架是配位聚合物的一部分，代表了大量替代能源应用的一个强大的新工具。通过提供定制的高表面积材料的简单的合成策略可以很容易获得MOF。

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