686506
m-Carborane-9-thiol
97%
Synonym(s):
1,7-Dicarba-closo-dodecaborane-9-yl-thiol, 9-Mercapto-1,7-dicarbadodecaborane (12)
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About This Item
Empirical Formula (Hill Notation):
C2H12B10S
CAS Number:
Molecular Weight:
176.29
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
Assay
97%
form
solid
mp
181-185 °C
SMILES string
SB1BB[C@H]2BBBBB[C@@H](B1)B2
InChI
1S/C2H12B10S/c13-12-7-2-3-1(6-11-12)4-8-10-9-5-2/h1-11,13H/t1-,2+/m1/s1
InChI key
LJIJIIVFZSYPTF-NCGGTJAESA-N
General description
m-Carborane-9-thiol is a carboranethiol that is used in the formation of self-assembled monolayers (SAMs) on a variety of surfaces.
Application
m-Carborane-9-thiol forms a SAM to tune the work function of gold and silver for potential applications in organic light emitting diodes (OLEDs). It can also be used in the synthesis of metal organic chalcogenides (MOC).
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Sterically controlled mechanochemistry under hydrostatic pressure
Yan H, et al.
Nature, 554(7693), 505-505 (2018)
Kai Kristiansen et al.
ACS nano, 8(10), 10870-10877 (2014-10-08)
Strong and particularly long ranged (>100 nm) interaction forces between apposing hydrophobic lipid monolayers are now well understood in terms of a partial turnover of mobile lipid patches, giving rise to a correlated long-range electrostatic attraction. Here we describe similarly
Interface control in organic electronics using mixed monolayers of carboranethiol isomers
Kim J, et al.
Nano Letters, 14(5), 2946-2951 (2014)
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