682500
Copper(I) thiophene-2-carboxylate
Synonym(s):
(2-Thiophenecarboxylato)copper, 2-Thiophenecarboxylic acid, copper complex, Cu (TC), Cuprous 2-thiophenecarboxylate
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About This Item
Empirical Formula (Hill Notation):
C5H3CuO2S
CAS Number:
Molecular Weight:
190.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1
SMILES string
[Cu]OC(=O)c1cccs1
InChI key
SFJMFSWCBVEHBA-UHFFFAOYSA-M
form
solid
reaction suitability
core: copper, reaction type: C-C Bond Formation, reagent type: catalyst
Quality Level
Application
Copper(I) thiophene-2-carboxylate can be used as a reactant or reagent in:
- Studies of xenobiotic response to herbicide safener derivatives.
- Synthesis of functionalized BODIPY dye analogs.
- Orthogonal cross-coupling reactions.
- Preparation of parent borondipyrromethene system.
- Copper mediated cross-coupling.
Reactant or reagent involved in:
- Studies of xenobiotic response to herbicide safener derivatives
- Synthesis of functionalized BODIPY dye analogs
- Orthogonal cross-coupling reactions
- Preparation of parent borondipyrromethene system
- Copper mediated cross-coupling
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Xenobiotic responsiveness of Arabidopsis thaliana to a chemical series derived from a herbicide safener.
Skipsey M, et al.
The Journal of Biological Chemistry, 286(37), 32268-32276 (2011)
N-Amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids.
Zhang Z, et al.
Organic Letters, 10(14), 3005-3008 (2008)
2?and 3?Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy.
Leen V, et al.
European Journal of Organic Chemistry, 2011(23), 4386-4396 (2011)
Regioselective Syntheses of 2, 3?Substituted Pyridines by Orthogonal Cross?Coupling Strategies.
Koley M, et al.
European Journal of Organic Chemistry, 2011(10), 1972-1979 (2011)
Zhihui Zhang et al.
Organic letters, 8(19), 4331-4333 (2006-09-08)
A new method for the synthesis of nitriles is described. As a complement to the classic cyanation of aryl halides using cyanide sources and a transition metal catalyst, the palladium-catalyzed cross-coupling of thiocyanates with boronic acids in the presence of
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