All Photos(1)
Synonym(s):
2-Methyl-N-(phenylthio)propan-2-amine, N-(1,1-Dimethylethyl)benzenesulfenamide
Empirical Formula (Hill Notation):
C10H15NS
CAS Number:
Molecular Weight:
181.30
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
97%
reaction suitability
reagent type: oxidant
refractive index
n20/D 1.5457
bp
57-60 °C/0.3 mmHg
density
0.997 g/mL at 25 °C
SMILES string
CC(C)(C)NSc1ccccc1
InChI
1S/C10H15NS/c1-10(2,3)11-12-9-7-5-4-6-8-9/h4-8,11H,1-3H3
InChI key
AAQBFMPKCDTAJD-UHFFFAOYSA-N
Application
Reactant for:
- Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes
- Anodic oxidation reactions
In the presence of NCS, this sulfenamide catalyzes the mild and selective oxidation of primary and secondary alcohols to the respective aldehydes and ketones.
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Teruaki Mukaiyama
Angewandte Chemie (International ed. in English), 43(42), 5590-5614 (2004-10-08)
This Review describes the basic concepts that have guided our exploration of new chemical reactions by giving examples of results from my research group. Our strategy of carrying out research is to investigate three to four different topics at a
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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