680214
N-Boc-4-piperidineacetaldehyde
97%
Synonym(s):
4-(2-Oxoethyl)piperidine-1-carboxylic acid, tert-butyl ester, tert-Butyl 4-(formylmethyl)piperidine-1-carboxylate
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About This Item
Empirical Formula (Hill Notation):
C12H21NO3
CAS Number:
Molecular Weight:
227.30
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
97%
form
solid
mp
38-42 °C
application(s)
peptide synthesis
functional group
aldehyde
SMILES string
[H]C(=O)CC1CCN(CC1)C(=O)OC(C)(C)C
InChI
1S/C12H21NO3/c1-12(2,3)16-11(15)13-7-4-10(5-8-13)6-9-14/h9-10H,4-8H2,1-3H3
InChI key
PSRHRFNKESVOEL-UHFFFAOYSA-N
Application
Reactant for synthesis of:
Reactant for:
- Pim-1 inhibitors
- Selective GPR119 agonists for type II diabetes
Reactant for:
- α-arylation of aldehydes
- Enantioselective α-benzylation of aldehydes via photoredox organocatalysis
- Enantioselective α−triflouromethylation of aldehydes
Building block employed in a synthesis of (S)-quinuclidine-2-carboxylic acid. Substrate used in an enanioselective organo-catalytic α-vinylation reaction.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
>230.0 °F
Flash Point(C)
> 110 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Tetrahedron Letters, 47, 2515-2515 (2006)
Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes.
Hahn Kim et al.
Journal of the American Chemical Society, 130(2), 398-399 (2007-12-22)
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